Decoding Superconductivity in La3Ni2O7−δ Thin Films via Ozone-Driven Structure and Oxidation Tuning

2026-08-07

Mathieu Flavenot

Hoshang Sahib

Jérôme Robert

Marc Lenertz

Gilles Versini

Laurent Schlur

Alexandre Gloter *

N. Viart

Daniele Preziosi *

DOI：10.1002/sstr.70542

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The discovery of superconductivity in bulk Ruddlesden-Popper La3Ni2O7(LNO327) under high hydrostatic pressure has redefined the recent experimental consensus that nickelate superconductivity is restricted to systems with a 3d9 electronic configuration and square-planar coordination. However, the structural and electronic prerequisites for stabilizing superconductivity, whether under pressure or at ambient conditions in the case of thin films, remain poorly understood, largely due to the metastable nature of the LNO327 phase. Here, we present a detailed structural study of epitaxial La3Ni2O7−δ thin films by using scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS). Grown via pulsed laser deposition onto SrLaAlO4 substrates, those films exhibit distinct superconducting properties as a function of the different post-annealing conditions used. By correlating the rich landscape of stacking polymorphs with transport behavior, this work establishes a framework for understanding the metastable superconducting phase in bilayer nickelate thin films. In particular, we found that the LNO-1313 stacking polymorph does not support superconductivity, suggesting it is not a superconducting phase. Our findings underscore the critical role of homogeneity in oxygen stoichiometry, epitaxial strain and structural motif in stabilizing superconductivity, offering a clear pathway for designing ambient-pressure superconducting nickelates.

Keywords:

bilayer nickelates

EELS

HAADF-STEM

PLD

Decoding Superconductivity in La3Ni2O7−δ Thin Films via Ozone-Driven Structure and Oxidation Tuning

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