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Deconvolution analysis of the thermal decomposition of samarium polysulfides

delete2026-06-13
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PRE
AI
I
I.O. Yurev *
K
Kanipa Ibraeva
М
Мaxim S. Моlokeev
A
Aleksandr S. Aleksandrovsky
D
Daria A. Kazantseva
V
Victoria M. Grigorchenko
O
O.V. Andreev
DOI：10.1016/j.jssc.2026.126172delete
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Abstract

Abstract

En 中文
• Fraser-Suzuki deconvolution resolves five overlapping DTG stages in SmS2-x. • Multiphase homologous mixtures exhibit a relaxation stage absent in ordered Sm10S19. • All decomposition trajectories converge to a single Sm4S7 intermediate. • Coexisting homologous phases produces Urbach tails in optical absorption spectra. • First experimental bandgaps of samarium polysulfides are reported.

Journal

Journal of Solid State Chemistry cover
Journal of Solid State Chemistry
IF:
3.5
Papers:
1.6W
Citations:
3.0W

Organization

F
federal research center ksc sb ras
Scholars:
74
Papers: 23
Citations: 0
U
University of Tyumen
Scholars:
74
Papers: 32
Citations: 0
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