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Defective nano-silica loaded polymeric carbon nitride for visible light driven CO2 reduction and dye degradation

delete2023-06-01
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OA
AI
T
Toshali Bhoyar
B
B. Moses Abraham
N
Nilesh R. Manwar
A
Akanksha Gupta
N
Naresh Mameda
S
Surendar Tonda
D
Devthade Vidyasagar *
S
Suresh S. Umare *
DOI:10.1016/j.catcom.2023.106692delete
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Abstract

Abstract

En 中文
A hybrid composite of polymeric carbon nitride (PCN) and defective nano-silica (n-SiOx) photocatalyst has been synthesized, exhibiting a high surface area, improved light response, and reduced charge recombination. The synergistic formation of PCN-n-SiOx interface facilitated photoinduced charge transfer from PCN to n-SiOx, resulting in suppressed carrier recombination. The resultant hybrid PCN-n-SiOx sample demonstrated a three-fold photocatalytic reduction of CO2 into methanol and formic acid. Furthermore, photoelectrocatalytic CO2 reduc-tion selectively yielded 283.0 mu mol L-1 of formic acid, a five-fold increment compared to bare PCN (57.0 mu mol L-1). These findings hold promise for the development of PCN-based hybrid composites for solar-powered applications.
Keywords:
Polymeric carbon nitride
Defective nano-silica
CO2 reduction
Photooxidation
Photoelectrocatalytic
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Journal

Catalysis Communications cover
Catalysis Communications
IF:
4.3
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6.6K
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Bar Ilan University
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indian institute of technology (iit) - kanpur
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national institute of technology (nit system)
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visvesvaraya national institute of technology, nagpur
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indian institute of technology system (iit system)
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