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Depolymerisation of poly(lactide) under continuous flow conditions
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DOI：10.1039/d4sc05891g.png)
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Abstract
En 中文
Poly(l-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer (CRM), where direct depolymerisation to l-lactide can be achieved. CRM of PLLA is typically impeded by thermal decomposition and side reactions, due to the high ceiling temperate (T-c) of PLLA in bulk (>600 degrees C), which preclude implementation on a large scale, and has led to the development of catalytic strategies, under vacuum or high dilution in high boiling point solvents conditions. In this study, a commercially available Sn(ii) catalyst and low boiling point solvents, at a range of temperatures and concentrations, were explored for the CRM of PLLA in a continuous flow process. The solvent THF was found to produce the best results, where up to 92% conversion of lactide could be achieved, with 92-97% selectivity for l-lactide formation at temperatures 150-170 degrees C. Further, inline monitoring of monomer and polymer concentrations in flow were used to determine the depolymerisation rate coefficient k(depo) and the activation energy of k(depo) was determined to be 129.4 kJ mol(-1).
Keywords:
POLYLACTIC ACID PLA
L-LACTIDE
POLY(L-LACTIC ACID)
HYDROLYTIC DEGRADATION
KINETICS
POLYMERIZATION
THERMODYNAMICS
PYROLYSIS
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