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Design and Use of Amphiphilic Polymers as Stabilizers in (Mini)emulsion Polymerization
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DOI：10.1016/j.progpolymsci.2026.102090.png)
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Abstract
En 中文
• Reviewed amphiphilic polymers as stabilizers in (mini)emulsion polymerization. • Outlined impact of stabilizer on particle size in (mini)emulsion polymerization. • Detailed how polymeric stabilizers influence rheological and film properties. • Highlighted applications of particles synthesized with polymeric stabilizers. • Provided outlook on polymeric stabilizers in (mini)emulsion polymerization.
Keywords:
Emulsion polymerization
miniemulsion polymerization
stabilization
amphiphilic polymers
rheological properties
films
latex applications
[I]
initiator concentration
[M]p
monomer concentration in polymer particles
[S]
stabilizer concentration
2-EHA
2-ethylhexyl acrylate
2OA
2-octyl acrylate
AA
acrylic acid
AAm
acrylamide
AGE
allyl glycidyl ether
AGET-ATRP
atom transfer radical polymerization with activators generated by electron transfer
AMPSNa
2-acrylamido-2-methylpropanesulfonic acid sodium
AMS
α-methylstyrene
AN
acrylonitrile
APi
N-acryloylpiperidine
APy
N-acryloylpyrrolidine
ASR
alkali-soluble resin
ATRP
atom transfer radical polymerization
BA
n-butyl acrylate
BACy
N,N’-bis(acryloyl) cystamine
BBOPP
biaxially oriented polypropylene
BCP
block copolymer
BMA
n-butyl methacrylate
Bn-Cys
benzyl-L-cysteine
BODIPY
4,4-difluoro-4-bora-3a,4a-diaza-s-indacene
BODIPYA
boron-dipyrromethene acrylate
BRC
block-random copolymer
BzMA
benzyl methacrylate
C13MA
C13 alkyl methacrylate
CAC
critical aggregation concentration
CCTP
catalytic chain transfer polymerization
ChNF
chitin nanofiber
CMC
critical micelle concentration
CMP
carboxymethylpullulan
CNC
cellulose nanocrystal
CTA
chain transfer agent
Cys
L-cysteine
DAAM
diacetone acrylamide
DEAMA
2-(diethylamino)ethyl methacrylate
DGlu
D-glucuronic acid
DHHB
2-(4-diethylamino-2-hydroxybenzoyl) benzoate
DMA*
dodecyl methacrylate
DMA
N,N-dimethylacrylamide
DMAEMA
2-(dimethylamino) ethyl methacrylate
DMC
(2-(acryloyloxy)ethyl)trimethylammonium chloride
DNS-86
allyloxy polyoxyethylene(10)nonyl ammonium sulfate
DSA
dodecenyl succinic anhydride
DSC
differential scanning calorimetry
DVB
divinylbenzene
Ɖ
dispersity
EA
ethyl acrylate
EDL
electrical double layer
EG
ethylene glycol
EGDMA
ethylene glycol dimethacrylate
EHA
ethyl hexyl acrylate
EO
ethylene oxide
FA
folate
FRET
Förster Resonance Energy Transfer
G’
storage modulus
G’’
loss modulus
GA
D-galactosamine
Glu
L-glutamic acid
GMA
glycidyl methacrylate
HBPAA
highly branched poly(acrylic acid)
HBPMA
highly branched poly(methyl acrylate)
HEA
2-hydroxyethyl acrylate
HEMAGl
2-{[(D-glucosamin-2-N-yl)carbonyl]oxy}ethyl methacrylate
HFBA
2,2,3,4,4,4-hexafluorobutyl acrylate
HFBMA
hexafluorobutyl methacrylate
HMA
hexyl methacrylate
iBMA
iso-butyl methacrylate
IBOA
isobornyl acrylate
IBOMA
isobornyl methacrylate
ISOMA
isosorbide (di)methacrylate
kp
propagation rate constant
LA
lactobionic acid
Leu
L-leucine
LGA
lactic-co-glycolic acid
LL
L-lysine
LMA
lauryl methacrylate
logP
logarithm of the octanol-water partition coefficient
MA
methyl acrylate
MAA
methacrylic acid
ManAm
mannose acrylamide
MFFT
minimum film formation temperature
MMA
methyl methacrylate
My
β-myrcene
n¯
n¯
average number of radicals per particle
NA
Avogadro’s number
Nagg
aggregation number
NaMA
sodium methacrylate
NBC NCA
S-(o-nitrobenzyl)-L-cysteine N-carboxyanhydride
NH-DHM
amino-functionalized with dihydromyrcenol moieties
NMP
nitroxide mediated polymerization
Np
number of particles
OEGMA
oligo(ethylene glycol) methyl ether methacrylate
oNB
o-nitrobenzyl
OPV
oligo(p-phenylenevinylene)
OSA
octenyl succinic anhydride
PA
phenyl alanine
PEG
poly(ethylene glycol)
PEGA
poly(ethylene glycol) methyl ether acrylate
PEGMA
poly(ethylene glycol) methacrylate
PEOA
poly(ethylene oxide) acrylate
Phe
L-phenylalanine
PISA
polymerization-induced self-assembly
PO
propylene oxide
PSA
pressure-sensitive adhesive
PVA
poly(vinyl acetate)
RAFT
reversible addition-fragmentation chain transfer
RDRP
reversible deactivation radical polymerization
ROP
ring opening polymerization
Rp
rate of polymerization
SA
stearyl acrylate
SANS
small-angle neutron scattering
SAXS
small-angle x-ray scattering
SDBS
4-dodecylbenzenesulfonic acid
SDS
sodium dodecyl sulfate
SEM
scanning electron microscopy
SLS
static light scattering
SMA*
stearyl methylacrylate
SMA
styrene-maleic anhydride
SNP
starch nanoparticle
St
styrene
STO
styrene oxide
tBA
t-butyl acrylate
tBMA
t-butyl methacrylate
TFEA
2,2,2-trifluoroethyl acrylate
THG
tetrahydrogeraniol
TMA
trimethylolpropane
TMAEMA
trimethylaminoethyl methacrylate
TMS
trimethylsilyl
TR-SANS
time-resolved small-angle neutron scattering
VBC
vinyl benzyl chloride
VBMC
7-(4-vinylbenzyloxy)-4-methylcoumarin
VOC
volatile organic compound
VT
ethylene tetrazole
Z-L-lysine
ε-carbobenzyloxy-L-lysine
ζ
zeta-potential
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