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Dibasic ammonium phosphate and phytic acid as alternative phosphate sources in sol-gel-derived 58S bioactive glass
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DOI：10.1016/j.jnoncrysol.2026.124150.png)
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Abstract
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• Phytic acid and diammonium hydrogen phosphate effectively incorporate phosphate during sol-gel synthesis, unlike triethyl phosphate. • In FIT samples, part of the phosphate segregates into crystalline phases, increasing silica‑network polymerization compared with FOS. • FOS samples contain phosphate groups with more non‑bridging oxygens, indicating predominantly terminal chain‑ending environments. • The absence of phosphate in TEP samples was not prohibitive to bioactivity, as hydroxyapatite formation still occurred.
Keywords:
Bioactive glass
Sol-gel
Phytate
Dibasic ammonium phosphate
Phosphate precursors
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