.png){kind=icon}
.png){kind=icon}
Return
Direct photochemical activation of non-heme Fe(IV)=O complexes
.png){kind=icon}
OA
AI
DOI：10.1039/c7cc07452b.png)
.png){kind=icon}
.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
Near-UV excitation of non-heme Fe-IV=O complexes results in light intensity dependent increase in reaction rates for the oxidation of C-H bonds even at low temperature (-30 degrees C). The enhancement of activity is ascribed to the ligand-to-[Fe-IV=O] charge transfer character of the near-UV bands to generate a highly reactive [(L+) Fe-III-O*] species. The enhancement is not observed with visible/NIR excitation of the d-d absorption bands.
Keywords:
IRON-OXO COMPLEXES
REACTIVITY
OXIDATION
AI Summary
Key information extracted from the uploaded paper, including a brief overview, abstract, background, key highlights, visual analysis, and future outlook.
Journal
IF:
4.2
Papers:
5.9W
Citations:
16.5W