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Dissolution kinetics of poly(styrene-co-acrylonitrile) below and above its glass transition temperature
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DOI：10.1016/j.mtcomm.2025.114556.png)
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Abstract
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• Dissolution enthalpy shifts from transition-driven below Tg to mixing above Tg. • Induction time in the poor solvent approaches that of the good solvent above Tg. • Below Tg, SAN dissolution is governed by segmental relaxations and diffusion. • Above Tg, SAN dissolution follows a diffusion-limited, Fickian mechanism.
Keywords:
Polymer dissolution
Physical recycling
Glass Transition
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