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Double stranded interwound infinite linear silver coordination network

delete2001-01-01
delete64
PRE
AI
B
Bruno Schmaltz
A
Abdelaziz Jouaiti
M
Mir Wais Hosseini
A
André De Cian
DOI:10.1039/b103824adelete
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Abstract

Abstract

En 中文
Upon self-assembly of a bismonodentate ligand based on two pyridine units interconnected at the para position by a hexaethylene glycol fragment using ester junctions and Ag+ cation, a double stranded interwound infinite linear network was obtained in the crystalline phase; the formation of this unprecedented architecture is a result of the loop type conformation of the connector segment which forms a pseudo-crown ether. The loop surounds the metal cation which is linearly coordinated to two pyridines belonging to consecutive units, thus forming the 1-D network.
Keywords:
STRUCTURAL-ANALYSIS
MOLECULAR TECTONICS
DESIGN
LIGAND
POLYMERS
CATION
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Journal

Chemical Communications cover
Chemical Communications
IF:
4.2
Papers:
5.9W
Citations:
16.5W

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