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Efficient separation of polyester/cotton blends using a deep eutectic solvent–NaOH hybrid system for textile recycling

delete2025-09-30
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PRE
AI
张乐乐 (Lele Zhang)
T
Tengfei Wang
王勇 (Yong Wang) *
D
Dongdong Ye
Z
Zongqian Wang *
DOI:10.1039/D5GC04525Hdelete
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Abstract

Abstract

En 中文
To overcome the key challenges in polyester (PET)/cotton blend separation—such as difficulty in separation; high energy use; and performance degradation—a green; innovative and efficient choline chloride/ethylene glycol deep eutectic solvent–sodium hydroxide (DES–NaOH) hybrid system was developed. Benefiting from the selective structural loosening of PET fibers by DES; confirmed by Raman imaging technology; which significantly accelerates degradation under alkaline conditions; this work achieves complete degradation and recycling of PET fibers under mild reaction conditions (dissolution temperature of 98 °C; duration time of 60 min; NaOH dosage of 5% w/v; and liquor ratio of 1 : 30). Importantly; high-purity terephthalic acid was recovered through acidification; precipitation; and filtration; while cotton fibers maintained structural integrity and properties with minimal mass loss (<3%); confirming the valuable; effective and selective separation process. This work offers an innovative; environmentally friendly; and cost-effective solution to the challenge of PET/cotton blend waste recycling.

Journal

Green Chemistry cover
Green Chemistry
IF:
9.2
Papers:
1.3W
Citations:
7.6W

Organization

A
Anhui Agricultural University
Scholars:
1.2W
Papers: 5.7K
Citations: 1.0W
W
Wuhu Fuchun Dyeing & Weaving Co., Ltd.
Scholars:
1
Papers: 1
Citations: 0