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Electrochemical growth and physical properties of Mg-Doped ZnO nanorods: An experimental and theoretical study
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DOI：10.1016/j.materresbull.2026.114369.png)
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Abstract
En 中文
• Mg-doped transparent conductive oxides ZnO nanorods were synthesized via two-step electrochemical deposition on ITO. • Mg incorporation induces lattice contraction, microstrain, and reduced crystallinity. • Nanorod diameter decreases systematically with Mg content due to modified growth kinetics. • Enhanced optical transparency and an increased band gap from 3.30 to 3.39 eV achieved through magnesium doping. • PL analysis reveals enhanced defect-related emission associated with strain and disorder. • DFT (TB-mBJ) calculations confirm bandgap widening and improved visible transmittance.
Keywords:
Electrodeposition
Mg doped ZnO
Transmittance
Gap energy
DFT calculation
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5.7
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1.3W
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2.9W
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