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Electrochemical kinetics, microkinetics modelling – a tutorial from basics to practical implementation
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DOI：10.1016/j.electacta.2026.149713.png)
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Abstract
En 中文
• The basics of electrochemical kinetics are introduced.
• Microkinetics modelling of the Redox E reaction is detailed.
• Extension to the more complex Volmer-Heyrovský mechanisms is given.
• The Butler-Volmer / Tafel equations and their conditions of application are given.
• When Butler-Volmer fails to capture the kinetics, more complex formalisms are available.
Keywords:
Electrochemical kinetics
Microkinetics modelling
Stationary conditions
Butler-Volmer equation
Marcus-Hush-Chidsey theory
Journal
IF:
5.6
Papers:
4.1W
Citations:
12.6W
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