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Electrochemical Potential–Driven Ion Migration and Interfacial Adsorption in Ionic Liquids
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DOI：10.1016/j.gce.2026.03.003.png)
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Abstract
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• Ion-specific electro-responsive nanofriction was revealed for imidazolium-based ionic liquids at charged organosilicon-modified Au interfaces. • Negative electrical potentials induced opposite frictional responses in structurally distinct ionic liquids, driven by differences in cation polarity and interfacial adsorption. • Short-range attractive interactions dominate adhesion-controlled nanofriction and link wettability to friction under applied potential
Keywords:
Nanofriction behavior
Electro-responsive interfaces
Wettability control
Ion adsorption
Ionic liquids
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