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Electrochemical reactions under reverse bias create additional mobile ions that enable hole tunneling in metal halide perovskite diodes
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DOI：10.1016/j.joule.2026.102577.png)
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Abstract
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• Electrochemistry creates mobile ions, causing low breakdown voltages near −5 V • More than 1018 cm−3 mobile ions are created in 3 min of reverse bias at −6 V • Hole-transport layers (HTLs) inhibit Pb reduction and limit mobile ion generation • Weak HTLs enable reduction, mobile ion creation, and cell degradation
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