Return
Electrosynthesis with split-bipolar electrodes
DOI:10.1016/j.coelec.2024.101443.png)
Abstract
En 中文
Bipolar electrochemistry has recently gained renewed interest as a valuable electrochemical technique for electrosynthesis applications. The peculiarity of this technology is the wireless mode of electrode reactions, that is redox processes can be driven on a conductive material, namely a bipolar electrode (BPE), without the need for an ohmic contact. A split-BPE (s-BPE) is a particular type of BPE, where two conductors are connected using an ammeter that is placed outside the electrolytic solution. While this configuration allows the two conductors to behave like a single BPE, the main advantage of such a system is that the current can be measured in situ, promoting the search for the optimized set of conditions for a successful electrosynthesis application. Herein, we review the latest trends in electrifying synthesis that exploit the concept of s-BPE for electrosynthesis of polymeric materials and electrochemical fluorination of small organic molecules.
Keywords:
Split-bipolar electrode
Bipolar electrochemistry
Electrosynthesis
Electropolymerization
Electrochemical fluorination
Journal
IF:
6.9
Papers:
1.7K
Citations:
8.6K
Organization
Cited Papers
Separation high voltage field driven on-chip amperometric detection in capillary electrophoresis
ANALYTICAL CHEMISTRY
IF6.7
Fabrication of One-Dimensional Polymer Nanowires by Templated Bipolar Electropolymerization Promoted by Electrophoretic Effect
MACROMOLECULES
IF5.2
Dual-channel bipolar electrode focusing: simultaneous separation and enrichment of both anions and cations
LAB ON A CHIP
IF5.4

