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Electrosynthesis with split-bipolar electrodes

delete2024-04-01
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OA
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E
Elena Villani
S
Shinsuke Inagi *
DOI:10.1016/j.coelec.2024.101443delete
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Abstract

Abstract

En 中文
Bipolar electrochemistry has recently gained renewed interest as a valuable electrochemical technique for electrosynthesis applications. The peculiarity of this technology is the wireless mode of electrode reactions, that is redox processes can be driven on a conductive material, namely a bipolar electrode (BPE), without the need for an ohmic contact. A split-BPE (s-BPE) is a particular type of BPE, where two conductors are connected using an ammeter that is placed outside the electrolytic solution. While this configuration allows the two conductors to behave like a single BPE, the main advantage of such a system is that the current can be measured in situ, promoting the search for the optimized set of conditions for a successful electrosynthesis application. Herein, we review the latest trends in electrifying synthesis that exploit the concept of s-BPE for electrosynthesis of polymeric materials and electrochemical fluorination of small organic molecules.
Keywords:
Split-bipolar electrode
Bipolar electrochemistry
Electrosynthesis
Electropolymerization
Electrochemical fluorination

Journal

Current Opinion in Electrochemistry cover
Current Opinion in Electrochemistry
IF:
6.9
Papers:
1.7K
Citations:
8.6K

Organization

I
Institute of Science Tokyo
Scholars:
3.2W
Papers: 2.7W
Citations: 117
Cited Papers

Cited Papers

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errAnand, Robbyn K.; Sheridan, Eoin; Knust, Kyle N.; Crooks, Richard M.
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Pressure-Driven Bipolar Electrochemistry
err2011-03-15
err31
PREAI
errDumitrescu, Ioana; Anand, Robbyn K.; Fosdick, Stephen E.; Crooks, Richard M.
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Fabrication of One-Dimensional Polymer Nanowires by Templated Bipolar Electropolymerization Promoted by Electrophoretic Effect
err2020-09-01
err12
PREAI
errZhou, Yaqian; Shida, Naoki; Koizumi, Yuki; Endo, Kaoru; Tomita, Ikuyoshi; Inagi, Shinsuke
errShare
errSave
errShare
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Dual-channel bipolar electrode focusing: simultaneous separation and enrichment of both anions and cations
err2012-01-01
err54
PREAI
errKnust, Kyle N.; Sheridan, Eoin; Anand, Robbyn K.; Crooks, Richard M.
errShare
errSave
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