1
Return

Engineering Pd/CeO2-TiO2 interfacial sites via a MOF-derived strategy for efficient solvent-free oxidation of benzyl alcohol

delete2026-08-01
delete0
PRE
AI
X
Xinyue Zhang
Z
Zhe Wang
X
Xin Zhao
Z
Ziyi Deng
D
Dongchen Li
X
X. Li *
DOI：10.1016/j.mcat.2026.116254delete
deleteOriginal
deleteOriginal request for help
deleteShare
deleteSave
Abstract

Abstract

En 中文
• MOF derived CeO2-TiO2 core-shell heterointerfaces were engineered for benzyl alcohol oxidation. • The CeO2-TiO2 interface suppresses phase transformation and sintering, enriching oxygen vacancies. • The optimized interface stabilizes abundant Pd2+ species and surface chemisorbed oxygen. • Pd/Ce0.10TiOx achieves 99.1% conversion, >93% selectivity, and a TOF of 36,226 h−1. • A volcano-type relationship links Ce/Ti ratio, Pd electronic state, oxygen species and the catalytic activity.
Keywords:
MOF derived
CeO2-TiO2 core-shell structure
Pd
Benzyl alcohol oxidation
Solvent free

Journal

Molecular Catalysis cover
Molecular Catalysis
IF:
4.9
Papers:
5.4K
Citations:
1.5W

Organization

T
taiyuan institute of technology
Scholars:
163
Papers: 72
Citations: 0
T
taiyuan university of technology
Scholars:
5.3K
Papers: 1.7K
Citations: 0
Cited Papers

Cited Papers

Citing Papers

Citing Papers