.png){kind=icon}
Return
Environmentally benign multiphase solid-liquid-gas catalysis
.png){kind=icon}
PRE
AI
DOI：10.1039/c9gc04063c.png)
.png){kind=icon}
Original request for help.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
It is significant for the environment that molecular oxygen replaces conventional heavy metal-containing or toxic oxidants to participate in oxidation reactions. However, the involved gas-oil-solid multiphase catalytic reactions usually show low reaction efficiency due to the low solubility of gas in oil. Herein, an organic-inorganic hybrid with certain interfacial activity was synthesized by using an alkoxysilane covalent modified POM. Such a hybrid POM has surface activity and can be adsorbed at the gas-liquid interface, and allows direct contact between the gas, oil and catalyst at the interface. The performance of the foam system is superior to that of the conventional multiphase catalytic reaction at room temperature. In addition, no solvent was required for the reaction. The catalyst can be recovered by centrifugation after the reaction.
Keywords:
SELECTIVE OXIDATION
SUPERCRITICAL CO2
AEROBIC OXIDATION
MOLECULAR-OXYGEN
ALCOHOLS
METAL
ACID
TRANSFORMATION
HYDROGENATION
DERIVATIVES
AI Summary
Key information extracted from the uploaded paper, including a brief overview, abstract, background, key highlights, visual analysis, and future outlook.
Journal
IF:
9.2
Papers:
1.3W
Citations:
7.6W
Organization
Cited Papers
ShareSavePreparation and characterization of new ruthenium and osmium containing polyoxometalates, [M(DMSO)3Mo7O24]4- (M = Ru(II), Os(II)), and their use as catalysts for the aerobic oxidation of alcohols.png)
INORGANIC CHEMISTRY
INORGANIC CHEMISTRYIF4.7
PREAI
ShareSaveStructural Transformation of Porous Polyoxometalate Frameworks and Highly Efficient Biomimetic Aerobic Oxidation of Aliphatic AlcoholsACS CATALYSIS
ACS CATALYSISIF13.1
PREAI
ShareSaveThe Polyoxovanadate-Based Carboxylate Derivative K6H[VV 17VIV 12(OH)4O60(OOC(CH2)4COO)8]•nH2O: Synthesis, Crystal Structure, and Catalysis for Oxidation of SulfidesINORGANIC CHEMISTRY
INORGANIC CHEMISTRYIF4.7
PREAI
ShareSaveLiquid phase hydrogenation of maleic anhydride to 1,4-butanediol in a packed bubble column reactor
PREAI
ShareSave
View more