F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance

2026-05-06

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Dahong Peng

Hongkang Su

Ziting Yan

Chenxu Li

Shilie Pan *

Min Zhang *

DOI：10.1016/j.mtchem.2026.103655

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• A systematic comparison of F−/OH− modified [B3O6]3- clusters shows that properties evolve with F−/OH− content. • By changing the type and arrangement of the fundamental building blocks, a breakthrough in dimensionality was achieved. • Tunable optical properties were achieved, namely, the birefringence across the series ranges from 0.013 to 0.112 at 546 nm.

Keywords:

F−/OH− modification

[B3O6] clusters

deep-ultraviolet

hydroxyfluorooxoborates

tunable optical properties

F−/OH− terminal modification of [B3O6] clusters: Constructing deep-ultraviolet hydroxyfluorooxoborates with tunable optical performance

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