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Facile Synthesis of Well-Defined Gradient 4-Vinylbenzyl-piperidine/β-Myrcene Copolymer via Living and Controlled Anionic Copolymerization under mild conditions

delete2026-06-15
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PRE
AI
Y
Yao Long
J
Jiahao Zhou
X
Xupeng Han
M
Min Zhang
Y
Yayan Wang
J
Jiaping Tan
M
Meilin Liu
L
Lijun Li *
K
Kun Liu *
DOI:10.1016/j.polymer.2026.130393delete
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Abstract

Abstract

En 中文
• 4-Vinylbenzyl piperidine was anionically copolymerized with β-myrcene to afford well-defined copolymers with controllable molecular weight (Mn) and narrow dispersity (Đ) above room temperature. • The copolymerization results are interpreted using the LAP chain-end active center coordination mechanism and the N-Li coordination synergy mechanism within the polymer chain. • This paper is of great significance for advancing the LAP sequence control theory and the synthesis of functional biomass-based rubber products.

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Polymer cover
Polymer
IF:
4.5
Papers:
2.5K
Citations:
6.1W

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