How Far Can We Push Polymer Architectures?

Patrick J. M. Stals

doi:10.1021/ja400890v

How Far Can We Push Polymer Architectures?

2013-03-12

99

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AI

Krzysztof Matyjaszewski

S

Sergei S. Sheiko

DOI：10.1021/ja400890v

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Abstract

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We here report the synthesis and characterization of a complex polymeric architecture based on a block copolymer with a cylindrical brush block and a single-chain polymeric nanoparticle block folded due to strong intramolecular hydrogen-bonds. The self-assembly of these constructs on mica surfaces was studied with atomic force microscopy, corroborating the distinct presence of block copolymer architectures.

Keywords:

TRANSFER RADICAL POLYMERIZATION

MOLECULAR BRUSHES

SYNTHETIC-POLYMERS

BLOCK-COPOLYMERS

SCALING THEORY

CROSS-LINKING

NANOPARTICLES

MACROMOLECULES

ADSORPTION

DENDRIMERS

How Far Can We Push Polymer Architectures?

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