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Hydrogeochemical Assessment of Lithium in Oilfield Formation Waters of the Mangystau Region, Kazakhstan: Distribution, Geochemical Controls, and Preliminary Resource Evaluation
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DOI：10.3390/chemengineering10070088.png)
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Abstract
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This study presents a hydrogeochemical assessment of oilfield formation waters from the Karazhanbas, Zhetybay, and Uzen oil fields in the Mangystau Region of Kazakhstan, with the aim of elucidating lithium distribution, identifying the geochemical factors controlling its accumulation, and providing a preliminary resource-oriented evaluation. The study investigated pH, total dissolved solids (TDS), ionic–salt composition, lithium (Li) concentration, and the relationships between Li, TDS, major cations, and geochemical ratios, including Ca/Li and Mg/Li. Major ions were determined using standard hydrochemical methods, while Li was analyzed by inductively coupled plasma optical emission spectrometry (ICP-OES). The investigated waters were predominantly classified as chloride–calcium type according to their hydrochemical composition. In terms of TDS, the waters follow the sequence Uzen > Zhetybay > Karazhanbas, whereas Li concentrations follow the sequence Zhetybay > Uzen > Karazhanbas. The highest Li concentrations were detected in Zhetybay waters (1.40–1.85 mg/dm3); in Uzen waters, Li reached 1.51 mg/dm3; and in Karazhanbas waters, it ranged from 0.30 to 0.70 mg/dm3. The highest Mg/Li and (Na+ + K+)/Li ratios were characteristic of Uzen waters, indicating a more complex salt matrix. Compared with internationally reported lithium-enriched brines, the Mangystau formation waters contain relatively low Li concentrations and cannot currently be considered a commercially viable lithium source. The scientific significance of this study lies in establishing a regional hydrogeochemical baseline for oilfield formation waters and demonstrating that maximum mineralization does not necessarily correspond to the highest Li concentration.
Keywords:
lithium
oilfield formation waters
hydrogeochemistry
Mangystau region
geochemical controls
critical raw materials
preliminary resource evaluation
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