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In Situ Grown ZnIn2S4@ZnWO4 Heterojunction for Highly Sensitive Photoelectrochemical Detection of Chlorogenic Acid
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DOI：10.1021/acssensors.5c04016.png)
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Abstract
En 中文
Chlorogenic acid (CA) is a phenolic acid compound with broad biological activity. In this study, a high-performance photoelectrochemical sensor based on in situ grown ZnIn2S4@ZnWO4 heterojunctions was developed for the sensitive detection of CA. ZnWO4 nanocrystals were successfully grown on the surface of flower-like ZnIn2S4 through a one-step hydrothermal method, resulting in a tightly coupled heterojunction structure that effectively promoted photo-induced charge separation and enhanced photocurrent response. Experimental results demonstrated that the sensor exhibited excellent analytical performance for CA, with a good linear relationship within a concentration range of 20–800 nM, a detection limit as low as 5 nM (S/N = 3), and high selectivity, stability, and reproducibility. Density functional theory (DFT) calculations revealed the charge transfer mechanism at the heterojunction interface and the interaction between CA and the material surface. Practical sample analysis showed that the sensor was successfully applied to accurately determine CA content in coffee, eucommia ulmoides oliver and lonicera japonica thunb, with recovery rates ranging from 97.08 to 103.56%. This study provides a new method for CA detection and offers fresh insights into the design of efficient photoelectrochemical sensors.
Keywords:
ZnWO4
ZnIn2S4
photoelectrochemical sensor
chlorogenic acid
density functional theory
s-scheme heterojunction
Journal
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9.1
Papers:
975
Citations:
2.6W
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