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Insights into lignin depolymerization through palladium-catalyzed hydrogenolysis of α-O-4 model compounds
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DOI：10.1016/j.fuproc.2026.108558.png)
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Abstract
En 中文
• Synthesis and hydrogenolysis of α-O-4 lignin model compounds including novel ones. • Kinetic studies reveal substituent effects on Pd-catalyzed hydrogenolysis. • Ortho-methoxy groups on the aryl moiety accelerate hydrogenolysis. • Methoxy and especially hydroxy groups on the benzyl moiety inhibit hydrogenolysis. • Insights into selective α-O-4 bond cleavage for lignin depolymerization.
Keywords:
Hydrogenolysis
Lignin model compounds
Kinetics
Valorization of lignin
Depolymerization
Biomass
Journal
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7.7
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6.8K
Citations:
2.7W
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