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Iridium corroles
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DOI：10.1021/ja801049t.png)
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Abstract
En 中文
This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 angstrom for 1 and 0.0325 angstrom for 2), the UV-vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(l]) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.
Keywords:
COMPLEXES
PORPHYRIN
EFFICIENT
SPECTROSCOPY
ACTIVATION
CATALYSTS
PYRROLE
METAL
IRON
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15.6
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