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Isolating intermediates

delete2022-09-27
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PRE
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Pavel A. Dub *
DOI：10.1038/s41557-022-01051-7delete
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Abstract

Abstract

En 中文
Noyori-type catalysts and inorganic bases are frequently used together for homogeneous hydrogenation, but key intermediates have not yet been isolated. Now, the structure and reactivity of a long-postulated intermediate - the alkali metal amidate complex - have been reported through experimental and computational studies.
Keywords:
HYDROGENATION

Journal

Nature Chemistry cover
Nature Chemistry
IF:
20.2
Papers:
4.4K
Citations:
4.8W

Organization

S
schrodinger, inc.
Scholars:
629
Papers: 287
Citations: 3