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Keggin type Cs5PW11O39M(II)(H2O) (M=Cu, Mn, and Co) sensitized silicon solar cell to achieve high photon-to-electron conversion efficiency
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DOI：10.1016/j.materresbull.2026.114203.png)
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Abstract
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• This work presents the first report of Keggin-type transition metal–substituted heteropolyanion-sensitized silicon composite photoelectric materials: Cs5PW11O39M(II)(H2O) (M=Cu, Mn, and Co). • Cs5PW11O39M(II)(H2O)/Si (M=Cu, Mn, and Co) composites with mastoid-like morphology possess enhanced photon-to-electron conversion efficiency. • This work originally bring Keggin-type transition metal–substituted heteropolyanions in the field of photoelectric conversion.
Keywords:
Keggin-type heteropolyanions
transition metal substitution
silicon composite
photoelectric conversion
photon-to-electron efficiency
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