arrow
Return

Liquid azide salts

delete2008-03-18
delete37
PRE
AI
T
Tommy Hawkins
M
M. Rosander
J
J. D. Mills
A
Adam Brand
L
L.M. Hudgens
G
Greg Warmoth
A
Ashwani Vij
DOI:10.1021/ic702068rdelete
deleteOriginal
deleteOriginal request for help
deleteShare
deleteSave
Abstract

Abstract

En 中文
Ionic liquid azides from azidoethyl, alkyl, and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles were prepared and examined for the first time to investigate their structural and physical properties. All reported salts possess melting points below 100 degrees C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.
Keywords:
HYBRID DFT COMPUTATION
X-RAY
POLYAZIDE CHEMISTRY
CRYSTAL-STRUCTURES
SPECTROSCOPIC CHARACTERIZATION
TELLURIUM(IV) AZIDES
HYDRAZINIUM AZIDE
N-AMINOAZOLES
N-15 NMR
DERIVATIVES

Journal

Inorganic Chemistry cover
Inorganic Chemistry
IF:
4.7
Papers:
4.9W
Citations:
10.5W

Organization

No organization information available