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Low-load Θ-metallacarboranes as safe and efficient photoredox catalysts for UVA-driven oxidation in water
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DOI：10.1016/j.xcrp.2025.102815.png)
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Abstract
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• High-yield photooxidation in water at catalyst loadings as low as 0.01 mol % • Catalyst efficiency differences at wavelengths arise from distinct excited states • θ-Metallacarboranes show enhanced UVA activity despite their naturally weak absorption • The most efficient excited state for chemical conversion is the lowest-energy one
Keywords:
photoredox catalysis
wavelength excitation
Fe(III) and Co(III)
photocatalysts
metallacarborane
multiconfigurational quantum chemistry
water-only catalysis
3d⁵ vs 3d⁶ comparison
Δo orbital splitting
new 3d catalysts
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