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Mechanistic insights in electrochemical C–N coupling reactions to urea
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DOI：10.1016/j.jmst.2026.03.079.png)
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Abstract
En 中文
• Systematically reveals the fundamental mechanisms of electrochemical C-N coupling, with a focus on the dominant pathways for CO2/nitrate and CO2/N2 reactions. • Identifies key reactive intermediates (e.g., *CO, *NH2, *NO2, *NO) governing selectivity and efficiency through integrated experimental and theoretical analysis. • Clarifies how catalyst microstructure steers reaction outcomes by modulating intermediate binding and conversion, providing a rationale for catalyst design.
Keywords:
Electrocatalysis
C–N coupling
Urea
Mechanisms
Catalysts
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Journal
J
IF:
14.3
Papers:
282
Citations:
0
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