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Metal-free POSS-based crosslinked polymers with triazole linkers as efficient single-component catalysts for CO2 conversion
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DOI：10.1016/j.jcou.2026.103440.png)
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Abstract
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• POSS-based ionic polymer enables efficient CO2/epoxide cycloaddition catalysis. • High activity was achieved under solvent- and cocatalyst-free conditions. • DFT reveals cooperative roles of I– and Si–OH in promoting epoxide activation.
Keywords:
Heterogeneous catalysis
Carbon dioxide
POSS
Cycloaddition
Epoxide
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