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Microdisplacement printing
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DOI：10.1021/nl050981j.png)
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Abstract
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We describe a new patterning technique that employs microcontact printing to replace preformed labile self-assembled monolayers (SAMs) selectively; we call this microdisplacement printing. We demonstrate that this technique results in ordered molecular regions of both the patterning (displacing) molecule as well as the remnant labile film, here 1-adamantanethiolate. The existence of the 1-adamantanethiolate SAM before patterning hinders lateral surface diffusion of the patterning molecules, and therefore permits the use of molecules that are otherwise too mobile to pattern by other methods.
Keywords:
SELF-ASSEMBLED MONOLAYERS
ALKANETHIOLS
KINETICS
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