.png){kind=icon}
.png){kind=icon}
Return
Modulating the structure of O3-type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 for high-performance sodium-ion batteries via Na2MoO4 reactive wetting coating combined with Mo doping and interface reconstruction
.png){kind=icon}
PRE
AI
DOI：10.1016/j.jcis.2025.01.087.png)
.png){kind=icon}
Original request for help.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
O3-type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 (NFM) is considered as a promising cathode material for sodium-ion batteries (SIBs) due to its high theoretical energy density and low production cost. However, the applications of NFM are restricted owing to detrimental interfacial side reactions and phase evolution during cycling. Herein, a three-in- one modification strategy, including Na2MoO4 coating, surface reconstruction from layered to spinel phase, and Mo6+ doping, is proposed to design NFM. A uniform and tight Na2MoO4 coating layer formed via reactive wetting mechanism can effectively inhibit the unfavorable side reactions between cathode and electrolyte. The formation of nanoscale spinel layer can anchor the interior layered structure, leading to a decrease in volume change during the sodiation/desodiation process. The incorporation of Mo6+ with a high valence state and strong Mo-O bonds into the O3 phase promotes the expansion of transition-metal layer spacing and enhances the structural stability. As a result, tri-modified NFM exhibits superior cycling stability with a capacity retention of 85.20 % after 300 cycles at 100 mA g-1 and rate performance with a discharge capacity of 56.9 mAh/g at 2000 mA g-1 , outperforming those of pristine NFM (61.76 % and 39.4 mAh/g). This synergistic modification approach provides a new avenue to improve the performance of layered-oxide cathode materials for SIBs.
Keywords:
Sodium-ion batteries
O3-type layered oxides
Mo6+doping
Na2MoO4 coating
Interface reconstruction
Reactive wetting
Journal
IF:
9.7
Papers:
3.7W
Citations:
14.7W
Organization
No organization information available