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Molecular imine cages with π-basic Au3(pyrazolate) faces
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DOI：10.1039/d3sc06280e.png)
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Abstract
En 中文
One tetrahedral and two trigonal prismatic cages with pi-basic Au-3(pyrazolate)(3) faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au-3(pyrazolate)(3) complexes in the prismatic cages augments the interaction with pi-acids, as demonstrated by the encapsulation of polyhalogenated aromatic compounds. The tetrahedral cage was found to act as a potent receptor for fullerenes. The structures of the three cages, as well as the structures of adducts with C-60 and C-70, could be established by X-ray crystallography.
Keywords:
COLUMNAR MESOPHASES
TRINUCLEAR COMPLEXES
LIGAND
DERIVATIVES
FULLERENES
HOSTS
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