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Monolithic AgX/Biomass Carbon Aerogels (X = Br, Cl) for Recyclable Photocatalytic Degradation of Multiple Pollutant Classes
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DOI：10.3390/gels12080711.png)
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Abstract
En 中文
While silver halides (AgX) are promising visible-light photocatalysts for water remediation, their practical deployment is severely hindered by intrinsic photocorrosion, rapid charge recombination, and macroscopic recovery challenges. Here, we demonstrate a monolithic AgX/biomass carbon aerogel composite platform, constructed by anchoring AgX nanocrystals in situ onto a 3D hierarchical carbon skeleton. The carbon network not only suppresses nanoparticle aggregation but also plays contrasting optical roles: amplifying the intrinsic visible-light absorption of AgBr while endowing the otherwise UV-confined AgCl with substantial visible-light response. Consequently, the optimal 30 wt% AgBr/CA composite achieves a 95.68% methylene blue degradation efficiency within 60 min—outperforming pristine AgBr by 2.6-fold—while establishing robust activity against two additional, structurally distinct pollutants: rhodamine B and the colorless antibiotic ciprofloxacin. Notably, the free-standing monolith retains exceptional activity over six consecutive cycles. Mechanistic investigations reveal that the carbon aerogel functions as an electron-accepting reservoir, which accelerates interfacial charge separation and steers electron flow toward superoxide radical generation. Notably, XRD and XPS analyses confirm that no detectable metallic Ag0 is present in the as-prepared composites. This work establishes a sustainable and scalable architectural paradigm for designing highly efficient, stable, and easily recyclable photocatalytic systems.
Keywords:
monolithic carbon aerogel
silver halide
electron reservoir
charge separation
multi-class pollutant degradation
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