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Multimetal-substituted pyrite-type NiS2 nanosheets for bifunctional electrocatalysis in alkaline media

delete2026-02-01
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OA
AI
Q
Qihao Cui
B
Baipo Shu
L
Liu, Yichun
Y
Yi Wan
R
Rongguang Xiao
F
Fenghao Nie
C
Can Wang
Y
Yunying Fan *
DOI:10.1016/j.ijoes.2026.101306delete
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Abstract

Abstract

En 中文
Efficient bifunctional electrocatalysts are vital for water electrolysis. We overcome limitations of sulfide catalysts by fabricating FeAlVNi dual-sulfide nanosheets via a quaternary synergy strategy. Fe/V dual-doping, validated by PDOS, enhances the density of states near the Fermi level. The nanowire structure ensures efficient charge transport (70 % lower impedance) and abundant active sites. In 1 M KOH, the catalyst shows low overpotentials of 214 mV (OER) and 88 mV (HER) at 10 mA cm-2, requiring only 1.65 V for overall water splitting. Fe/V optimize electronic structure while Al enhances stability, offering new insights for designing multicomponent sulfide catalysts.
Keywords:
Nanosheets
Metal sulfides
Multimetal synergy
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Journal

International Journal of Electrochemical Science cover
International Journal of Electrochemical Science
IF:
2.4
Papers:
1.2K
Citations:
1.6W

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K
kunming university of science & technology
Scholars:
1.9K
Papers: 495
Citations: 0
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