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Optimal nickel loading balances dispersion and mesoporosity for efficient ethanol-CO2 reforming to hydrogen-rich syngas
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DOI:10.1016/j.fuel.2026.140838.png)
Abstract
En 中文
• Ni/MSNs (5–20 wt% Ni) synthesized by CTAB sol–gel and ultrasonic impregnation. • 10 wt% Ni/MSNs exhibited 68–72% ethanol conversion and up to 61% H2 yield. • CO2 conversion reached up to 90% with H2/CO maintained at 1.1–1.5. • Optimized 10 wt% Ni/MSNs showed minimal carbon deposition (<1.5 wt%). • High Ni loadings caused Ni agglomeration, pore blockage, and stronger RWGS.
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