.png){kind=icon}
.png){kind=icon}
Return
Palladium-Catalyzed divergent access to benzylic thioesters and thioethers from sulfonyl chlorides via C–O bond activation
.png){kind=icon}
PRE
AI
H
C
H
T
X
Z
DOI：10.1016/j.jcat.2026.117109.png)
.png){kind=icon}
Original request for help.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
• The benzyl ethers as competent electrophiles in carbonylative C–S bond formation via C–O activation. • A metal-carbonyl-controlled divergent platform enabling switchable access to thioesters or thioethers from identical feedstocks. • Broad substrate scope, good functional group tolerance, and the use of odorless, stable sulfonyl chlorides as practical sulfur sources. • Mechanistic insights into the pentafluoropyridine-mediated C–O activation pathway and the distinct reaction manifolds for thioester versus thioether formation.
Journal
J
IF:
6.5
Papers:
1.2W
Citations:
5.1W
Organization
Cited Papers