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Phase control in vanadium recovery via matrix-introduced interfacial atomic diffusion
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DOI：10.1016/j.jhazmat.2026.142915.png)
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Abstract
En 中文
• MIIAD enables diffusion-controlled phase selectivity in solid-state reactions. • Fe2O3 matrix directs Ca/V diffusion and suppresses Ca-rich vanadates. • CaV2O6 is stabilized even under excess CaO via diffusion control. • DFT and STEM reveal diffusion hierarchy governing phase formation. • MIIAD enables energy-efficient vanadium extraction under mild leach.
Keywords:
Solid-solid reactions
Phase selectivity
Interface engineering
Fe2O3-rich matrix
MIIAD
Journal
IF:
11.3
Papers:
4.0W
Citations:
24.0W
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