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Photoacid-Mediated Controllable Gelation in a Chemical Reaction Cycle
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DOI：10.1002/syst.70037.png)
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Abstract
En 中文
We explore the use of a photoacid in a chemical reaction cycle, which allows for the controlled sol-to-gel transition of a saccharide aldehyde-based self-assembling system. The modulation of the pH with light enables to generate chemical fuels in situ, thus triggering monomer activation and gelation. Our efforts represent a promising step toward dissipative self-assembled systems with a higher degree of spatiotemporal control.
Keywords:
hydrogel
light-responsive
photoacid
chemical reaction cycle
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