Photocycloaddition in transition-metal complexes and their coordination frameworks: Design, reactivity, and structural insights

Donghyeon Kim

doi:10.1016/j.ccr.2026.218018

Photocycloaddition in transition-metal complexes and their coordination frameworks: Design, reactivity, and structural insights

2026-05-07

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PRE

AI

D

Donghyeon Kim

Z

Zakir Ullah

C

Chanyoung Seo

I

Ilkyu Han

H

Hyun You Kim

H

Hyotcherl Ihee *

DOI：10.1016/j.ccr.2026.218018

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Abstract

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• Photocycloadditions in 3d, 4d, and 5d transition-metal complexes and their coordination frameworks are examined. • Late transition metals readily serve as structural templates, whereas early/middle metals mostly function as photocatalysts. • Solid-state reactivity changes across diverse coordination geometries and phase transitions are summarized. • SCSC transformations and diverse photomechanical behaviors in crystals are highlighted. • Future directions are outlined for fundamental photochemistry, material science, and robotics.

Keywords:

Photocycloaddition

Transition-metal complexes

Coordination frameworks

Solid-state reactivity

Photomechanical behavior

Photocycloaddition in transition-metal complexes and their coordination frameworks: Design, reactivity, and structural insights

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