Polyimine networks based on 5-hydroxymethylfurfural with robust, intrinsically flame-retardant, photothermal self-healing, antioxidant, and water-resistant properties

Jialiang Zhong

doi:10.1016/j.eurpolymj.2026.114979

Polyimine networks based on 5-hydroxymethylfurfural with robust, intrinsically flame-retardant, photothermal self-healing, antioxidant, and water-resistant properties

2026-07-26

0

PRE

AI

J

Jialiang Zhong

Y

Yue Wang

W

Wenjie Mo

R

Rongji Shen

Y

Yanning Zeng *

DOI：10.1016/j.eurpolymj.2026.114979

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• 5-Hydroxymethylfurfural (HMF)-based PIs were synthesized. • HMF-based PIs exhibit V-0 flame retardancy without additives. • NIR-triggered self-healing with 97.4% efficiency at 1.42 W·cm−2. • Closed-loop recyclable with 81.9% strength retention after three cycles. • Dynamic imine networks combine recyclability, self-healing, and flame retardancy.

Polyimine networks based on 5-hydroxymethylfurfural with robust, intrinsically flame-retardant, photothermal self-healing, antioxidant, and water-resistant properties

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