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Polymer based materials for solid electrolyte sensors

delete2012-10-01
delete4
PRE
AI
C
C. Vonau *
J
J. Zösel
P
Paramasivam Muthusamy
K
K. Ahlborn
F
Frank Gerlach
V
V. Vashook
U
U. Guth
DOI:10.1016/j.ssi.2012.04.015delete
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Abstract

Abstract

En 中文
Electrochemical solid electrolyte sensors based on Yttria Stabilised Zirconia (YSZ) with mixed potential electrodes are suited for in-situ measurements of low concentrations of combustibles like hydrogen, carbon monoxide or hydrocarbons and also nitrogen oxides. The parameters sensitivity, selectivity and long-term stability of these sensors are correlated mainly with the performance of the electrode material. This work is directed on the investigation of newly developed conductive polymer composite materials (CPC) based on polyaniline (PANI). These materials have been characterised with respect to their morphology, thermal stability, catalytic activity and electrochemical behaviour on solid electrolytes in gases containing hydrogen, ethene and propene. For the first time it could be demonstrated, that CPC, consisting of PANI and different metal oxides or metal salts can be used at high temperature measurement up to temperatures of 450 degrees C because of improved thermal properties. (C) 2012 Elsevier B.V. All rights reserved.
Keywords:
Conductive polymer composite
Solid electrolyte
Potentiometric gas sensor
Mixed potential

Journal

Solid State Ionics cover
Solid State Ionics
IF:
3.3
Papers:
1.1W
Citations:
2.3W

Organization

L
Leipzig University
Scholars:
2.0W
Papers: 1.6W
Citations: 17
C
council of scientific & industrial research (csir) - india
Scholars:
4.7W
Papers: 3.9W
Citations: 37
T
Technische Universitat Dresden
Scholars:
3.2W
Papers: 2.5W
Citations: 249
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