Preparation, Characterization, and Mechanistic Considerations for 1,1,1-Tri(thioacetyl)ethane and 1,1-Di(thioacetyl)ethene

doi:10.1021/acs.joc.3c00377

Preparation, Characterization, and Mechanistic Considerations for 1,1,1-Tri(thioacetyl)ethane and 1,1-Di(thioacetyl)ethene

2023-05-03

0

PRE

AI

DOI：10.1021/acs.joc.3c00377

Original

Original request for help

Save

Abstract

En 中文

Two new compounds, 1,1,1-tri(thioacetyl)ethane and 1,1di(thioacetyl)ethene, arose during reactions of acetyl methoxy(thiocarbonyl) sulfide with potassium methyl xanthate. Relevant mechanisms were elucidated, which in turn suggested novel streamlined routes to these same compounds. Several further transformations of the title compounds were demonstrated, suggesting their potential synthetic utility.

Preparation, Characterization, and Mechanistic Considerations for 1,1,1-Tri(thioacetyl)ethane and 1,1-Di(thioacetyl)ethene

Abstract

Journal

Organization