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Recent trends in all-organic polymer dielectrics for high-temperature electrostatic energy storage capacitors

delete2025-05-01
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PRE
AI
Z
Zongliang Xie
L
Lu Fan
H
He Li
Z
Zhaoyu Ran
L
Lai, Shiqi
X
Xiaoyan Liu
A
Ashlin Deatherage
Y
Yalin Wang
黎琪 cover
黎琪 (Qi Li)
Y
Yi Yin
DOI:10.1016/j.progpolymsci.2025.101957delete
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Abstract

Abstract

En 中文
Electrostatic energy storage (EES) capacitors are critical for renewable energy and high-power systems, driving the search for dielectric materials that combine superior electrical insulation, mechanical flexibility, low density, cost-effectiveness, and processability. Polymer-based dielectrics have emerged as leading candidates, particularly for high electric field applications. However, conventional polymers often fail to meet the demands of high-temperature environments due to increased electrical conductivity and reduced discharged energy density at elevated temperatures, resulting in energy loss and reduced performance. High glass transition temperature (Tg) polymers show promise but require further optimization to enhance their energy storage capabilities under thermal and electrical stress. This review provides a comprehensive update on recent advancements in high-Tg polymer-based dielectrics for EES capacitors, focusing on both intrinsic polymers and all-organic composites. It outlines key design principles, critical performance parameters, and innovative strategies-such as nanofiller doping, layered architectures, physical blending, and chemical crosslinking-to improve electrical, thermal, and mechanical properties. The review also highlights emerging trends, including the integration of machine learning algorithms to explore novel polymer structures and expand the chemical design space. By bridging the gap between academic research and industrial application, this review aims to accelerate the development of next-generation dielectric materials capable of balancing multiple performance metrics for high-temperature EES capacitors. (c) 2025 Elsevier Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies.
Keywords:
All-organic polymer composites
Capacitors
Electrostatic energy storage
Heat resistant
Polymer dielectrics

Journal

Progress in Polymer Science cover
Progress in Polymer Science
IF:
26.1
Papers:
1.4K
Citations:
3.0W

Organization

No organization information available