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Removing multiplicities from activity coefficient models
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DOI：10.1016/j.fluid.2026.114732.png)
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Abstract
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• Complete analysis of binary interaction parameter multiplicities occurring in the NRTL and UNIQUAC models. • Elimination of multiplicities without restricting the range of activity coefficients the NRTL and UNIQUAC models can represent. • One-to-one mapping from activity coefficient to binary interaction parameter offers advantages in parameter fitting.
Keywords:
Activity coefficient models
Multiplicities
Thermodynamics
NRTL
UNIQUAC
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