logo
CanyamAI summaries for academic research
language
MobileMobile
  • Phone FeatureWeChat Mini Program
EnglishEnglish
noticeNotice
BlogBlog
delete
arrow
Return

Single-Crystalline UiO-67-Type Porous Network Stable to Boiling Water, Solvent Loss, and Oxidation

delete2018-05-21
delete20
PRE
AI
Y
Yan‐Lung Wong
K
Ka-Kit Yee
Y
Yun‐Long Hou
李加乾 cover
李加乾 (Jiaqian Li)
Z
Zuankai Wang
M
Mat­thias Zeller
A
A.D. Hunter
Z
Zhengtao Xu *
DOI：10.1021/acs.inorgchem.8b00404delete
deleteOriginal
deleteOriginal request for help
deleteShare
deleteSave
Abstract

Abstract

En 中文
With methylthio groups flanking the carboxyl groups, the 3,3',5,5'-tetrakis(methylthio)biphenyl dicarboxylate (TMBPD) linker forms a zirconium(IV) carboxylate porous framework featuring the topology of the UiO-67 prototype, i.e., with a face-centered-cubic array of the Zr6O4(OH)(4) clusters. Thioether functionalization proves valuable because the ZrTMBPD crystal is found to be exceptionally stable not only upon long-term exposure to air but also in boiling water and a broad range of pH conditions. The hydrophobicity of the metal-organic framework can also be tuned by simple H2O2 oxidation, as illustrated in the water contact-angle measurement of the pristine and H2O2-treated ZrTMBPD solid.
Keywords:
METAL-ORGANIC FRAMEWORKS
OIL-SPILL
STABILITY
ADSORPTION
FLUORESCENCE
TOPOLOGY
MOLECULE
THIOL
AI Summary

AI Summary

Key information extracted from the uploaded paper, including a brief overview, abstract, background, key highlights, visual analysis, and future outlook.

Journal

Inorganic Chemistry cover
Inorganic Chemistry
IF:
4.7
Papers:
4.9W
Citations:
10.5W

Organization

Purdue University System cover
Purdue University System
Scholars:
3.9W
Papers: 3.6W
Citations: 66
C
City University of Hong Kong
Scholars:
2.3W
Papers: 3.0W
Citations: 6.1W
P
Purdue University
Scholars:
2.6W
Papers: 2.0W
Citations: 147
researcher View more organizations