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Spontaneous macrocyclization through multiple dynamic cyclic aminal formation
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DOI：10.1039/d0cc07184f.png)
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Abstract
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The use of aminals in dynamic covalent chemistry is slightly underexplored, probably due to their inherent instability. Here we report the spontaneous [2+2] macrocyclization of tetrakis(aminals). Their unexpected stability and structural modularity, the dynamic nature of the connections and their water tolerance make them appealing systems for future applications as stimulus-responsive materials.
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4.2
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5.9W
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16.5W