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Squaramide-functionalized coordination capsule as hydrogen-bond-donor catalyst for efficient Friedel-Crafts alkylation
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DOI：10.1039/d6cc01883a.png)
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Abstract
En 中文
A squaramide-functionalized tetranuclear coordination capsule was constructed as an efficient catalyst for Friedel-Crafts alkylation. The supramolecular architecture suppresses self-association and creates a confined cavity enriched with directional hydrogen-bonding sites. This defined microenvironment enables substrate encapsulation, promotes activation, and stabilizes a preorganized conformation, thereby accelerating the nucleophilic addition step.
Keywords:
squaramide-functionalized coordination capsule
Friedel-Crafts alkylation
hydrogen-bond-donor catalyst
supramolecular architecture
nucleophilic addition
Journal
IF:
4.2
Papers:
5.9W
Citations:
16.5W
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Cited Papers