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Stabilizing Fluorine-π Interactions
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DOI：10.1002/anie.201702950.png)
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Abstract
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A series of N-arylimide molecular balances were designed to study and measure fluorine-aromatic (F-pi) interactions. Fluorine substituents gave rise to increasingly more stabilizing interactions with more electron-deficient aromatic surfaces. The attractive F-pi interaction is electrostatically driven and is stronger than other halogen-pi interactions.
Keywords:
electrostatic interactions
fluorine
F-pi interactions
supramolecular chemistry
pi interactions
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