.png){kind=icon}
Return
STIBATHIOLANES - SYNTHESIS, SOLID-STATE STRUCTURE, AND SOLUTION BEHAVIOR
.png){kind=icon}
PRE
AI
DOI：10.1021/ja00001a024.png)
.png){kind=icon}
Original request for help.png){kind=icon}
Share.png){kind=icon}
Save
Abstract
En 中文
The first examples of a new class of main group metallacycles, stibathiolanes, have been synthesized via transmetalation from zirconocene metallacycles. The X-ray crystal structures of three 1-halostibathiolanes have been determined and the compounds found to be polymeric in the crystalline state. Physical and spectroscopic data indicate that the compounds are monomeric in hydrocarbon solution but that they undergo rapid-reversible halide-exchange reactions. A consequence of one of these exchange reactions is the inversion of stereochemistry at antimony. The processes have been investigated by using a variety of NMR and crossover experiments. The proposed intermediate for the inversion of stereochemistry at the metal center is supported by the solid-state structures of the compounds in which the proposed connectivity of the intermediate is crystallographically established.
Keywords:
ISOMERICALLY PURE 1,3-DIENES
METAL-PROMOTED CYCLIZATION
RAY CRYSTAL-STRUCTURE
ZIRCONOCENE COMPLEXES
1,4-DIIODO 1,3-DIENES
INSITU GENERATION
ZIRCONIUM
ALKYNES
CARBONYLATION
ALKENES
AI Summary
Key information extracted from the uploaded paper, including a brief overview, abstract, background, key highlights, visual analysis, and future outlook.
Journal
IF:
15.6
Papers:
20.0W
Citations:
60.2W
Organization
No organization information available
Cited Papers
No cited papers available